NEW COMPLEXES OF TITANIUM WITH BIS(TRIMETHYLSILYL)AMIDO LIGANDS

被引：19

作者：

BAI, Y

ROESKY, HW

NOLTEMEYER, M

机构：

[1] Inst. F. Anorg. Chemie, D. Univ., Göttingen, W-3400

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1991年 / 595卷 / 04期

关键词：

TITANIUM COMPLEX COMPOUNDS; CYCLOPENTADIENYL TITANIUM BIS(TRIMETHYLSILYL)AMIDO COMPOUNDS; SYNTHESES; CRYSTAL STRUCTURE;

D O I：

10.1002/zaac.19915950104

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of cp'TiCl3 with LiN(SiMe3)2.Et2O 1 yield the compounds cp'TiCl2N(SiMe3)2 (cp' = C5H5 2, C5H4SiMe3 3, C5H3(SiMe3)2 4, C5Me5 5) and cp'TiCl[N(SiMe3)2]2 (cp' = C5H5 6). Compound 2 was characterized by an X-ray structural analysis with space group P2(1)/n and unit cell dimensions of a = 1660.9(7), b = 688.6(3), c = 1739.1(8) pm and beta = 117.18(3)-degrees.

引用

页码：21 / 26

页数：6

共 14 条

[1] AMONOONEIZER EH, 1966, INORG SYNTH, V8, P19
[2] 4,4-BIS-PI-CYCLOPENTADIENYL)-2,2-DIMETHYL-1-TRIMETHYLSILYLAZA-2-SILA-4-TITANACYCLOBUTANE - NOVEL ORGANOMETALLIC HETEROCYCLE
BENNETT, CR
BRADLEY, DC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1974, (01) : 29 - 30
[3] REACTIONS OF TRIMETHYLSILYLCYCLOPENTADIENE DERIVATIVES WITH TITANIUM, NIOBIUM, AND TANTALUM HALIDES
CARDOSO, AM
CLARK, RJH
MOORHOUSE, S
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1980, (07): : 1156 - 1160
[4] CRYSTAL-STRUCTURES OF TRICHLORO(ETA-5-CYCLOPENTADIENYL)TITANIUM(IV) AND ZIRCONIUM(IV)
ENGELHARDT, LM
PAPASERGIO, RI
RASTON, CL
WHITE, AH
[J]. ORGANOMETALLICS, 1984, 3 (01) : 18 - 20
[5] CRYSTAL STRUCTURE OF DIETHYLAMINOTITANIUM TRICHLORIDE
FAYOS, J
MOOTZ, D
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1971, 380 (02): : 196 - &
[6] SYNTHESIS, STRUCTURE, AND REACTIVITY OF ARYLOXO(IMIDO)TITANIUM COMPLEXES
HILL, JE
PROFILET, RD
FANWICK, PE
ROTHWELL, IP
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1990, 29 (06) : 664 - 665
[7] HILL JE, 1990, ANGEW CHEM, V102, P713
[8] COMPARATIVE REACTIVITY OF CYCLOPENTADIENE WITH IVB-ELEMENT AND VB-ELEMENT LIGANDS - REACTIONS WITH VB-ELEMENT HALIDES AND TITANIUM TETRACHLORIDE
JUTZI, P
KUHN, M
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 173 (02) : 221 - 229
[9] (C5ME5)SIME3 AS A MILD AND EFFECTIVE REAGENT FOR TRANSFER OF THE C5ME5 RING - AN IMPROVED ROUTE TO MONOPENTAMETHYLCYCLOPENTADIENYL TRIHALIDES OF THE GROUP-4 ELEMENTS
LLINAS, GH
MENA, M
PALACIOS, F
ROYO, P
SERRANO, R
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 340 (01) : 37 - 40
[10] Noltemayer M., 1989, ANGEW CHEM, V101, P788

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