STRUCTURE DU BIS(PI-ALLYLHIMACHALENE)-ALPHA,ALPHA-DICHLORODIPALLADIUM

被引：10

作者：

CHIARONI, A ^{[1
]}

RICHE, C ^{[1
]}

ELFIRDOUSSI, L ^{[1
]}

BENHARREF, A ^{[1
]}

KARIM, A ^{[1
]}

机构：

[1] UNIV CADI AYYAD,FAC SCI SEMLALIA,DEPT CHIM,MARRAKECH,MOROCCO

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷

关键词：

D O I：

10.1107/S0108270192010552

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of beta-himachalene with palladium(II) chloride gives bis(chloro)bridged cyclopalladated dimers with high regioselectivity. The allyl groups adopt a cis arrangement to one another resulting in a pseudo C2 axis in the complex. The palladium is coordinated along the alpha face of himachalene, the less hindered face of the molecule. The PdCl2 core is bent with a dihedral angle Cl-Pd-Pd-Cl of 112.3(1)degrees.

引用

页码：365 / 368

页数：4

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