INTERMOLECULAR COUPLINGS BETWEEN VINYL TRIFLATES AND ALLYLIC CUPRATES - A MILD AND RAPID ATYPICAL ROUTE TO 1,4-DIENES

被引：49

作者：

LIPSHUTZ, BH

ELWORTHY, TR

机构：

[1] Department of Chemistry, University of California, Santa Barbara

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 06期

关键词：

D O I：

10.1021/jo00293a002

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment Of Vinyl Triflates With Several Different Cyanocuprates Containing Allylic Ligands Leads To Coupling Products In Good Yields. Cuprates Containing Allyl, Methallyl, Crotyl, And Prenyl Groups All Participate In These Reactions Which Take Place Instantly At Low Temperatures. Highly Functionalized Substrates May Also Be Used. © 1990, American Chemical Society. All rights reserved.

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页码：1695 / 1696

页数：2

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