ETA-3-ALLYL COMPLEXES OF TUNGSTEN .1. PREPARATION AND REACTIONS OF [(ETA-3-C3H5)3WCL]2

被引：8

作者：

BENN, R ^{[1
]}

BROCK, TH ^{[1
]}

DIAS, MCFB ^{[1
]}

JOLLY, PW ^{[1
]}

RUFINSKA, A ^{[1
]}

SCHROTH, G ^{[1
]}

SEEVOGEL, K ^{[1
]}

WASSMUTH, B ^{[1
]}

机构：

[1] MAX PLANCK INST COAL RES,W-4330 MULHEIM,GERMANY

来源：

POLYHEDRON | 1990年 / 9卷 / 01期

关键词：

D O I：

10.1016/S0277-5387(00)84243-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An improved synthesis of (η3-C3H5)4W from W(OPh)6, and allylmagnesium bromide is reported. The further reaction with HX (X = Cl, Br) or iodine leads to [(η3-C3H5)3WX] 2 compounds, which in turn react with donor ligands to form the adducts (η3-C3H5)3W(L)X. Treatment of (η3-C3H5)3W(PMe3 )Cl with RMgX (R = Me, Et) produces the tungsten-alkyl compounds (η3-C3H5)3W(PMe 3)R. © 1990.

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页码：11 / 22

页数：12

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