DYNAMIC PROPERTIES OF FAST-ION-CONDUCTING BORATE GLASSES

被引：22

作者：

BALKANSKI, M ^{[1
]}

WALLIS, RF ^{[1
]}

DEPPE, J ^{[1
]}

MASSOT, M ^{[1
]}

机构：

[1] UNIV PARIS 06,PHYS SOLIDES LAB,F-75252 PARIS 05,FRANCE

来源：

MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY | 1992年 / 12卷 / 03期

关键词：

D O I：

10.1016/0921-5107(92)90300-X

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The effect of adding modifiers and dopants on the structural and conducting properties of fast ion conducting borate glasses is studied, experimentally with the aid of Raman and infrared spectroscopy, and theoretically using network dynamics and lattice dynamics calculations. In particular, the effects of Li2O as a modifier, and LiX (X = F, Cl, Br, I) and Li2SO4 as a dopant are discussed. The modifier is found to change the structure of the glass matrix through which the lithium ions, supplied by the dopant, must diffuse. These structural modifications are analyzed and discussed in reference to their effect on the resulting ionic conductivity.

引用

页码：281 / 298

页数：18

共 31 条

[1] EFFECT OF COULOMB INTERACTIONS BETWEEN FREE LITHIUM IONS ON THE ELECTRICAL-CONDUCTIVITY OF BORATE GLASS MODIFIED BY LI2O AND DOPED WITH LI2SO4 [J].

BALKANSKI, M ;

WALLIS, RF ;

DEPPE, J .

MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 1989, 3 (1-2) :65-68

[2] FREE LITHIUM ION CONDUCTION IN LITHIUM BORATE GLASSES DOPED WITH LICL OR LI2SO4 [J].

BALKANSKI, M ;

WALLIS, RF ;

DARIANIAN, I ;

DEPPE, J .

MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 1988, 1 (01) :15-21

[3]

BALKANSKI M, 1988, NATO ADV STUDY I SER, V199, P109

[4] NUCLEAR MAGNETIC-RESONANCE STUDIES OF GLASS STRUCTURE [J].

BRAY, PJ .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1985, 73 (1-3) :19-45

[5]

BRAY PJ, 1982, J NON-CRYST SOLIDS, V52, P45, DOI 10.1016/0022-3093(82)90280-0

[6]

BRILL TW, 1976, PHILLIPS RES REP S, V2

[7]

Brodsky M. H., 1975, Light scattering in solids, P205

[8]

CAZANELLI E, 1983, J CHEM PHYS, V79, P2615

[9] LATTICE-DYNAMICS AND NETWORK-DYNAMICS STUDIES OF VIBRATIONAL-MODES IN LITHIUM-DOPED BORATE GLASSES [J].

DEPPE, J ;

BALKANSKI, M ;

WALLIS, RF .

PHYSICAL REVIEW B, 1990, 41 (11) :7767-7773

[10] VIBRATIONAL-SPECTRA AND THE STRUCTURE OF PURE VITREOUS B2O3 [J].

GALEENER, FL ;

LUCOVSKY, G ;

MIKKELSEN, JC .

PHYSICAL REVIEW B, 1980, 22 (08) :3983-3990

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