A CHEMOENZYMATIC APPROACH TO ENANTIOMERICALLY PURE (R)-2,3-EPOXY-2-(4-PENTENYL)-PROPANOL, AND (S)-2,3-EPOXY-2-(4-PENTENYL)-PROPANOL, A CHIRAL BUILDING BLOCK FOR THE SYNTHESIS OF (R)-FRONTALIN AND (S)-FRONTALIN

被引：13

作者：

FERRABOSCHI, P ^{[1
]}

CASATI, S ^{[1
]}

GRISENTI, P ^{[1
]}

SANTANIELLO, E ^{[1
]}

机构：

[1] UNIV MILAN, DIPARTIMENTO CHIM & BIOCHIM MED, VIA SALDINI 50, I-20133 MILAN, ITALY

来源：

TETRAHEDRON-ASYMMETRY | 1993年 / 4卷 / 01期

关键词：

D O I：

10.1016/S0957-4166(00)86004-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Enantiomerically pure (R)- and (S)-epoxyalcohols 1, chiral intermediates for the synthesis of (R)- and (S)-frontalin 2, are prepared by Pseudomonas fluorescens lipase-catalyzed transesterification in dichloromethane.

引用

页码：9 / 12

页数：4

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