IONIZATION OF STRONG ELECTROLYTES .11. MOLECULAR STATES OF NITRIC ACID AND PERCHLORIC ACID

被引:53
作者
REDLICH, O
DUERST, RW
MERBACH, A
机构
[1] Lawrence Radiation Laboratory, Departments of Chemistry and Chemical Engineering, University of California, Berkeley, CA
[2] National Bureau of Standards, Washington
[3] Institut de Chimie Minérale et Analytique, Université de Lausanne
关键词
D O I
10.1063/1.1670541
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Recent proton magnetic measurements in the ternary systems HNO 3-DNO3-water and HClO4-DClO4water partly confirm older data and furnish new information on the molecular states of the acids, on hydration and solvation of the hydrogen ion, and on the distribution of H in deuterated acids between the ion and water. The dissociation constants of HNO3 and DNO3 between 0° and 65° are derived from the measurements.
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页码:2986 / &
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