COMPLEX FORMATION BY N-SUBSTITUTED ACETOACETAMIDES .3. STABILITIES OF DIVALENT METAL CHELATES OF ACETOACETANILIDES

被引：31

作者：

HARRIES, HJ

SAVAGE, S

WRIGHT, G

LOGAN, N

机构：

[1] Department of Chemistry, Derby and District College of Technology, Derby, England

[2] Department of Chemistry, University of Nottingham, Nottingham, England

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1969年 / 31卷 / 08期

关键词：

D O I：

10.1016/0022-1902(69)80580-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Acetoacetanilide and its derivatives have been examined as chelating agents for divalent metal ions in 50%(v/v) and 75%(v/v) aqueous dioxan. Acid dissociation constants were determined potentiometrically and values related to electronic effects of substituents. Stability constants of the Be(II), Co(II), Ni(II) and Cu(II) chelates were related to acid dissociation constants and to the metal. © 1969.

引用

页码：2477 / &

共 24 条

[1] PREDICTION OF STRENGTHS OF ORGANIC ACIDS
BARLIN, GB
PERRIN, DD
[J]. QUARTERLY REVIEWS, 1966, 20 (01): : 75 - &
[2] BJERRUM J, 1941, METAL AMINE FORMATIO, P35
[3] STABILITY OF CHELATE COMPOUNDS
CALVIN, M
WILSON, KW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1945, 67 (11) : 2003 - 2007
[4] CONWAY BE, 1952, ELECTROCHEMICAL DATA, P196
[5] HAMMETT LP, 1940, PHYSICAL ORGANIC CHE, pCH7
[6] HARNED HS, 1950, PHYSICAL CHEMISTRY E, P548
[7] COMPLEX FORMATION BY N-SUBSTITUTED ACETOACETAMIDES .2. STABILITIES OF DIVALENT METAL COMPLEXES OF N-(U-PYRILYL)-ACETOACETAMIDE
HARRIES, HJ
[J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1967, 29 (09): : 2484 - &
[8] COMPLEX FORMATION BY N-SUBSTITUTED ACETOACETAMIDES .1. ACID DISSOCIATION CONSTANTS AND STABILITY CONSTANTS OF THE BERYLLIUM COMPLEXES
HARRIES, HJ
[J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1963, 25 (05): : 519 - 523
[9] THE STABILITY OF TRANSITION-METAL COMPLEXES
IRVING, H
WILLIAMS, RJP
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1953, (OCT): : 3192 - 3210
[10] METHODS FOR COMPUTING SUCCESSIVE STABILITY CONSTANTS FROM EXPERIMENTAL FORMATION CURVES
IRVING, H
ROSSOTTI, HS
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1953, (NOV): : 3397 - 3405

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