OXYPYROLYSIS OF NATURAL-GAS

被引：43

作者：

MIMOUN, H ^{[1
]}

ROBINE, A ^{[1
]}

BONNAUDET, S ^{[1
]}

CAMERON, CJ ^{[1
]}

机构：

[1] INST FRANCAIS PETR, DIRECT RECH CINET & CATALYSE, 1 AVE BOIS PREAU, BP 311, F-92506 RUEIL MALMAISON, FRANCE

来源：

APPLIED CATALYSIS | 1990年 / 58卷 / 02期

关键词：

D O I：

10.1016/S0166-9834(00)82295-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The IFP oxypyrolysis process for the conversion of natural gas to olefins combines the oxidative coupling of methane, a heterogeneously catalysed reaction producing ethane as a primary product, with the steam cracking of ethane, a homogeneous gas-phase reaction producing ethylene and hydrogen as primary products. In the presence of added ethane, the oxidative coupling of methane proceeds at lower methane conversion and C2+ selectivity. However, if the ethane is added to the post-catalyst bed region of the reactor after the majority of molecular oxygen has been consumed, both methane conversion and C2+ selectivity remain high while a substantial portion of the added ethane is converted to ethylene plus hydrogen. This process is therefore able to upgrade all the alkane components, not only the methane, in natural gas. © 1990.

引用

页码：269 / 280

页数：12