THE LIF SPECTRA AND THE STRUCTURE OF JET-COOLED 4-(9-ANTHRYL)-N,N-DIMETHYLANILINE (ADMA)

被引：17

作者：

KAJIMOTO, O ^{[1
]}

HAYAMI, S ^{[1
]}

SHIZUKA, H ^{[1
]}

机构：

[1] GUNMA UNIV,DEPT CHEM,KIRYU,GUNMA 376,JAPAN

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 177卷 / 02期

关键词：

D O I：

10.1016/0009-2614(91)90071-G

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The LIF spectra of (9-anthryl)dimethylaniline (ADMA) were obtained in a jet-cooled condition. The 0-0 band appears as a train of complex peaks ranging from 370 to 380 nm with decreasing intensity towards longer wavelength. The analysis of these peaks reveals that the equilibrium angle between the anthracene and the benzene planes only slightly deviates from 90-degrees in the ground state, whereas in the S1 state the angle is about 60-degrees.

引用

页码：219 / 222

页数：4

共 10 条

[1]

GRABOWSKI ZR, 1979, NOUV J CHIM, V3, P443

[2] HIGH-PRESSURE STUDY OF VISCOSITY EFFECTS ON INTRAMOLECULAR EXCITED COMPLEX-FORMATION IN 9,9'-BIANTHRYL AND 4-(9-ANTHRYLMETHYL)-N,N-DIMETHYLANILINE [J].