THE STUDIES OF METAL-ION CATALYZED CARBON-HYDROGEN INSERTION OF ALPHA-ALKOXY-ALPHA'-DIAZOKETONES DERIVED FROM MANDELIC AND LACTIC ACIDS

被引：13

作者：

HON, YS ^{[1
]}

CHANG, RC ^{[1
]}

CHAU, TY ^{[1
]}

机构：

[1] NATL CHUNGHSING UNIV,DEPT CHEM,TAICHUNG,TAIWAN

来源：

HETEROCYCLES | 1990年 / 31卷 / 10期

关键词：

D O I：

10.3987/COM-90-5515

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The cupric acetylacetonate is the best catalyst to induce the carbon-hydrogen inserted reaction for the α-alkoxy-α′-diazoketones derivatives (5 and 6). The side reactions such as aromatic carbon-hydrogen insertion and rearrangement could be prevented. © 1990.

引用

页码：1745 / 1750

页数：6

共 7 条

[1] DIASTEREOSELECTIVITY IN THE SYNTHESIS OF 3(2H)-FURANONES - TOTAL SYNTHESIS OF (+)-MUSCARINE
ADAMS, J
POUPART, MA
GRENIER, L
[J]. TETRAHEDRON LETTERS, 1989, 30 (14) : 1753 - 1756
[2] RHODIUM ACETATE CATALYZES THE ADDITION OF CARBENOIDS ALPHA-OXYGENS TO ETHER OXYGENS
ADAMS, J
POUPART, MA
GRENIER, L
SCHALLER, C
OUIMET, N
FRENETTE, R
[J]. TETRAHEDRON LETTERS, 1989, 30 (14) : 1749 - 1752
[3] STEREOSELECTIVE SYNTHESIS OF ENDO-1,3 DIMETHYL-2,9 DIOXABICYCLO[3.3.1] NONANE
ADAMS, J
FRENETTE, R
[J]. TETRAHEDRON LETTERS, 1987, 28 (41) : 4773 - 4774
[4] BURKE SD, 1979, ORG REACTIONS, V26, P378
[5] WOLFF REARRANGEMENT OF ALPHA-DIAZO CARBONYL-COMPOUNDS
MEIER, H
ZELLER, KP
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1975, 14 (01): : 32 - 43
[6] REGIOCONTROL BY ELECTRON WITHDRAWING GROUPS IN THE RH-CATALYZED C-H INSERTION OF ALPHA-DIAZOKETONES
STORK, G
NAKATANI, K
[J]. TETRAHEDRON LETTERS, 1988, 29 (19) : 2283 - 2286
[7] CYCLOPENTANE CONSTRUCTION BY RH2(OAC)4-MEDIATED INTRAMOLECULAR C-H INSERTION - STERIC AND ELECTRONIC EFFECTS
TABER, DF
RUCKLE, RE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (24) : 7686 - 7693

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