DIELS-ALDER REACTIONS WITH AN ALPHA,BETA-UNSATURATED ALDEHYDO-SUGAR - A ROUTE TO 6-OXABICYCLO[3.2.1]OCTANES

被引：8

作者：

GALAN, ER ^{[1
]}

CHAMIZO, MJ ^{[1
]}

SERRANO, JA ^{[1
]}

机构：

[1] UNIV EXTREMADURA,FAC CIENCIAS,DEPT QUIM ORGAN,E-06071 BADAJOZ,SPAIN

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 11期

关键词：

D O I：

10.1016/S0040-4039(00)60786-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Thermal and catalytic Diels-Alder reactions of 1 with 2,3-dimethyl-1,3-butadiene gave 4-formyl-5-glycocyclohexenes 2 and 3. Absolute configurations at the new chiral centers in the addutcs are based on polarimetric correlation with known compounds. On reduction and acid treatment, the adducts 2 and 3 were converted into 6-oxabicyclo[3.2.1]octanes 13 and 15.

引用

页码：1811 / 1814

页数：4

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