ACCELERATION OF THE CONJUGATE ADDITION OF TI ATE ENOLATES VIA LEWIS-ACID CATALYSIS

被引：4

作者：

BERNARDI, A ^{[1
]}

CAVICCHIOLI, M ^{[1
]}

SCOLASTICO, C ^{[1
]}

机构：

[1] CNR, CTR SOSTANZE ORGAN NAT, I-20133 MILAN, ITALY

来源：

TETRAHEDRON | 1993年 / 49卷 / 47期

关键词：

D O I：

10.1016/S0040-4020(01)80244-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The conjugate addition of Ti ''ate'' complexes of ketone enolates to a alpha,beta-unsaturated ketones can be accelerated by activating the substrate via complexation with t-BuMe2SiCl or trityl triflate.

引用

页码：10913 / 10916

页数：4

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