SYNTHESIS OF A BIS-MANGANESE WATER-SPLITTING COMPLEX

被引：72

作者：

WATKINSON, M ^{[1
]}

WHITING, A ^{[1
]}

MCAULIFFE, CA ^{[1
]}

机构：

[1] UNIV MANCHESTER, INST SCI & TECHNOL, DEPT CHEM, MANCHESTER M60 1QD, LANCS, ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 18期

关键词：

D O I：

10.1039/c39940002141

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Complex 8 has been prepared by an efficient one-step manganese-templated condensation/macrocyclisation;upon irradiation using visible light in water in the presence of p-benzoquinone, complex 8 demonstrates the ability to split water.

引用

页码：2141 / 2142

页数：2

共 13 条

[1] THE ROLE OF MANGANESE IN PHOTOSYNTHETIC OXYGEN EVOLUTION [J].

AMESZ, J .

BIOCHIMICA ET BIOPHYSICA ACTA, 1983, 726 (01) :1-12

[2] A NOVEL MANGANESE(III) DIMER WITH AN EXTREMELY LONG MN-MN DISTANCE [J].

ASHMAWY, FM ;

BEAGLEY, B ;

MCAULIFFE, CA ;

PARISH, RVD ;

PRITCHARD, RG .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (13) :936-937

[3] WATER PHOTOLYSIS .1. THE PHOTOLYSIS OF COORDINATED WATER IN [(MNL-(H2O))2][CLO4]2 (L = DIANION OF TETRADENTATE O2N2-DONOR SCHIFF-BASES) - A MODEL FOR THE MANGANESE SITE IN PHOTOSYSTEM-II OF GREEN PLANT PHOTOSYNTHESIS [J].

ASHMAWY, FM ;

MCAULIFFE, CA ;

PARISH, RV ;

TAMES, J .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (07) :1391-1397

[4]

BERMEJO MR, 1994, J CHEM SOC CHEM COMM, P1153

[5]

DISMUKES GC, 1982, PHOTOBIOCH PHOTOBIOP, V3, P243

[6] THE METAL CENTERS OF THE PHOTOSYNTHETIC OXYGEN-EVOLVING COMPLEX [J].

DISMUKES, GC .

PHOTOCHEMISTRY AND PHOTOBIOLOGY, 1986, 43 (01) :99-115

[7]

GARCIADIEBE A, 1991, J CHEM SOC CHEM COMM, P729

[8] THE STATE OF MANGANESE IN THE PHOTOSYNTHETIC APPARATUS .3. LIGHT-INDUCED-CHANGES IN X-RAY ABSORPTION (K-EDGE) ENERGIES OF MANGANESE IN PHOTOSYNTHETIC MEMBRANES [J].

GOODIN, DB ;

YACHANDRA, VK ;

BRITT, RD ;

SAUER, K ;

KLEIN, MP .

BIOCHIMICA ET BIOPHYSICA ACTA, 1984, 767 (02) :209-216

[9]

GOVINDJEE, 1985, PHOTOCHEM PHOTOBIOL, V42, P187

[10]

HECK RF, 1985, PALLADIUM REAGENTS O, pCH6

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