EARLY HYDRATION OF TRICALCIUN SILICATE - A SOLID REACTION WITH INDUCTION AND ACCELERATION PERIODS

被引:66
作者
KONDO, R
DAIMON, M
机构
[1] Research Laboratory of Engineering Materials, Tokyo Institute of Technology, Tokyo, Meguro-ku
关键词
D O I
10.1111/j.1151-2916.1969.tb09203.x
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The hydration of tricalcium silicate was studied using a sample with a limited particle size distribution. The hydration reaction was analyzed as an example of general solid reactions having induction and acceleration periods. The first product, which may have a structure similar to the reactant, forms on the surfaces of reactant grains. The nuclei of the stable product are produced in the first product layer and act as reaction centers; the main reaction to form a stable product occurs rapidly in the acceleration period. in the hydration of calcium silicates, hydrates produced in this stage are poorly crystalline and metastable and change gradually into a more stable form. Copyright © 1969, Wiley Blackwell. All rights reserved
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页码:503 / &
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