STRUCTURAL RESEARCHES ON METAL-COMPLEXES WITH LIGANDS CONTAINING THE PYRIDOXAL MOIETY - X-RAY STRUCTURE OF CHLORO(N-PYRIDOXYLIDENE-N'-SALICYLOYLHYDRAZINATO)COPPER(II) MONOHYDRATE

被引：21

作者：

DOMIANO, P ^{[1
]}

MUSATTI, A ^{[1
]}

NARDELLI, M ^{[1
]}

PELIZZI, C ^{[1
]}

PREDIERI, G ^{[1
]}

机构：

[1] UNIV PARMA, CNR, CTR STUDIO STRUTTURIST DIFFRATTOMETRICA, I-43100 PARMA, ITALY

来源：

TRANSITION METAL CHEMISTRY | 1979年 / 4卷 / 06期

关键词：

D O I：

10.1007/BF00623975

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The x-ray crystal structure of the title complex is described Crystals are monoclinic, space group P21/n, with unit-cell dimensions:a=18.070(2), b=13.471(2), c=6.788(2) Å, β=94.70(1){ring operator}, Z=4. The structure was solved from diffractometer data by Patterson and Fourier methods and refined by least-squares techniques to R=5.0% for 2451 independent reflections. It consists of complex molecules, in which the copper atom square planar coordination comprises the chlorine atom, Cu-Cl=2.240(3) Å, and the organic ligand which acts as terdentate through the oxygen atom [Cu-O=1.948(3) Å] and a nitrogen atom, [Cu-N=1.933(5) Å] from the hydrazidic chain and the oxygen atom, [Cu-O = 1.894(4) Å] from the pyridoxal group. © 1979 Verlag Chemie, GmbH.

引用

页码：351 / 354

页数：4

共 21 条

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