SYNTHESES AND SYNTHETIC STUDIES OF 2-HYDROXY-5-(PROPARGYLOXY)BENZOIC ACID

被引:2
作者
BROWN, AB [1 ]
WHITLOCK, HW [1 ]
机构
[1] UNIV WISCONSIN,DEPT CHEM,SAMUEL M MCELVAIN LABS ORGAN CHEM,MADISON,WI 53706
基金
美国国家科学基金会;
关键词
D O I
10.1080/00397919308020397
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The title compound (1-1 is best made by selective 5-O-propargylation of methyl gentisate, followed by in situ saponification. Direct propargylation of gentisic acid gives a mixture of propargyl ethers, which surprisingly includes the 2-monoether.
引用
收藏
页码:23 / 34
页数:12
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