GIANT ORGANOMETALLIC NETWORKS DERIVED FROM FERROCENEPOLYSULFIDES

被引:44
作者
GALLOWAY, CP [1 ]
RAUCHFUSS, TB [1 ]
机构
[1] UNIV ILLINOIS,MAT RES LAB,URBANA,IL 61801
来源
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 09期
关键词
D O I
10.1002/anie.199313191
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Desulfurization with tributylphosphane converts the ferrocenepolysulfide 1 into three‐dimensional network polymers. These consist of ferrocene subunits interconnected by oligosulfide crosslinks. Gel permeation chromatography on an analogous polymerized alkyl derivative of 1 indicates molecular weights in excess of 106 Da. •=Fe. (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany
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页码:1319 / 1321
页数:3
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