A BRANCHED POLYSILANE

被引:21
作者
LAMBERT, JB
PFLUG, JL
ALLGEIER, AM
CAMPBELL, DJ
HIGGINS, TB
SINGEWALD, ET
STERN, CL
机构
关键词
D O I
10.1107/S0108270194009704
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
2,2,5,5-Tetrakis(trimethylsilyl)-1,1,1,3,3,4,4,6,6,6-decamethylhexasilane, C22H66Si10, is a polysilane in which the longest chain is made up of six Si atoms and branching occurs at the second and fifth Si atoms. Each of the two central Si atoms is bonded to a tris(trimethylsilyl)silyl group in an anti arrangement. Bond lengths and angles are sufficiently close to normal to indicate that the molecule is relatively unstrained.
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页码:713 / 715
页数:3
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