OXIDATION OF STEROIDAL KETONES .7. CLEAVAGE OF STEROIDAL CONJUGATED KETONES WITH RUTHENIUM TETROXIDE

被引：62

作者：

PIATAK, DM

BHAT, HB

CASPI, E

机构：

[1] Worcester Foundation for Experimental Biology, Shrewsbury

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 01期

关键词：

D O I：

10.1021/jo00838a027

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ruthenium tetroxide has been utilized for the cleavage of conjugated and cross-conjugated steroidal ketones. In some instances the yields have been superior to those found for ozone. The unexpected formation of enediones has been observed in the oxidation of 1,4-diene-3,11-diones. © 1969, American Chemical Society. All rights reserved.

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页码：112 / &

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