STEREOSPECIFIC HYDROGENOLYSIS OF BENZYL-TYPE ALCOHOLS

被引：44

作者：

MITSUI, S

KUDO, Y

KOBAYASH.M

机构：

[1] Department of Applied Science, Faculty of Engineering, Tohoku University, Sendai

来源：

TETRAHEDRON | 1969年 / 25卷 / 09期

关键词：

D O I：

10.1016/S0040-4020(01)82813-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In order to obtain additional information regarding the stereospecificity of hydrogenolysis on Co and Cu as well as Ni and Pd, optically active methyl 3-hydroxy-3-phentybutyrate, 3-hydroxy-3-phenylvaleric acid, methyl 3-hydroxy-3-phenylvalerate and 3-phenylpentan-1,3-diol were hydrogenolysed. In the hydrogenolysis on Ni, Co and Cu, the configuration was retained whereas on Pd the inversion of configuration occurred as reported for other compounds. © 1969.

引用

页码：1921 / &

共 25 条

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