共 5 条
SYNTHETIC STUDIES TOWARDS PASPALICINE .2. SYNTHESIS OF THE EASTERN HALF
被引:5
作者:
GUILE, S
[1
]
SAXTON, JE
[1
]
THORNTONPETT, M
[1
]
机构:
[1] UNIV LEEDS,SCH CHEM,LEEDS LS2 9JT,W YORKSHIRE,ENGLAND
关键词:
D O I:
10.1016/S0040-4039(00)79673-0
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
The synthesis of the pentacyclic beta-pyrone diketal(4), which constitutes rings D-G of the indolic mould metabolite paspalicine with the correct relative stereochemistry, is described. The structure and stereochemistry of the ketal (4) and its precursor diol (5) have been established by single crystal X-ray diffraction analysis.
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页码:1381 / 1384
页数:4
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