STEREOSPECIFIC SYNTHESIS OF A NOVEL ALLENIC CYCLOHEXANOID EPOXIDE FROM THE FUNGUS EUTYPA-LATA

被引：16

作者：

GORDON, J ^{[1
]}

TABACCHI, R ^{[1
]}

机构：

[1] UNIV NEUCHATEL,INST CHIM,51 AVE BELLEVAUX,CH-2000 NEUCHATEL,SWITZERLAND

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1992年 / 57卷 / 17期

关键词：

D O I：

10.1021/jo00043a035

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The stereospecific synthesis of the novel allenic cyclohexanoid epoxide 13 is reported. Key steps include Diels-Alder reaction between a 1,4-dioxygenatedbuta-1,3-diene 1 and a ketene equivalent 2 and the coupling of a mixed isopropenyl cuprate with propagylic sulfinate 10.

引用

页码：4728 / 4731

页数：4

共 26 条

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