STRUCTURE AND PROPERTIES OF A BIMETALLIC COMPLEX WITH A CONJUGATED BRIDGE BETWEEN IRON ATOMS IN 2 MACROCYCLES

被引：28

作者：

MOUNTFORD, HS

SPREER, LO

OTVOS, JW

CALVIN, M

BREWER, KJ

RICHTER, M

SCOTT, B

机构：

[1] UNIV PACIFIC,DEPT CHEM,STOCKTON,CA 95211

[2] UNIV CALIF BERKELEY,LAWRENCE BERKELEY LAB,BERKELEY,CA 94720

[3] WASHINGTON STATE UNIV,DEPT CHEM,PULLMAN,WA 99164

来源：

INORGANIC CHEMISTRY | 1992年 / 31卷 / 05期

关键词：

D O I：

10.1021/ic00031a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structure of a unique dinuclear bis-macrocyclic iron complex with a conjugated link between the low-spin iron(II) ions has been determined. This compound has unusually short iron-imine nitrogen bond lengths; it also has an intense near-infrared electronic transition (lambda = 874 nm, epsilon = 14 000 M-1 cm-1) that is assigned to an MLCT. Each iron has two axial CH3CN ligands.

引用

页码：717 / &

共 10 条

[1] STRUCTURE OF A NOVEL DIMER FORMED BY COUPLING METAL MACROCYCLES [J].