ROELEN,OTTO, PIONEER IN INDUSTRIAL HOMOGENEOUS CATALYSIS

被引:189
作者
CORNILS, B
HERRMANN, WA
RASCH, M
机构
[1] TECH UNIV MUNICH,INST ANORGAN CHEM,D-85747 GARCHING,GERMANY
[2] THYSSEN STAHL AG,D-47161 DUISBURG,GERMANY
来源
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 21期
关键词
D O I
10.1002/anie.199421441
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Otto Roelen discovered the oxo synthesis (hydroformylation) in 1938, and despite all the problems created by the war years he was able to explore successfully the fundamental aspects related to its application up to the point of building the first plant. At the same time he laid the groundwork for industrial utilization of homogeneous organometallic catalysts. Almost simultaneously, his contemporary, Walter Hieber, was investigating the basic chemistry of the same catalysts, but with no knowledge whatsoever of their potential application. Hydroformylation today constitutes one of the most important industrial examples of a homogeneous catalytic process. For corrigendum see DOI: Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany
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页码:2144 / 2163
页数:20
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