FLOW CALORIMETER FOR CONDENSABLE GASES AT LOW-TEMPERATURES AND HIGH-PRESSURES .2. COMPILATION OF EXPERIMENTAL RESULTS AND COMPARISON WITH PREDICTIONS BASED ON A MODIFIED REDLICH-KWONG EQUATION OF STATE

被引:31
作者
VANKASTEREN, PHG
ZELDENRUST, H
机构
[1] Koninklijke/Shell-Laboratorium, Amsterdam (Shell Research B. V.), Amsterdam-Noord
来源
INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS | 1979年 / 18卷 / 04期
关键词
D O I
10.1021/i160072a008
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The enthalpy-temperature relationships of methane, ethane, propane, nitrogen, and binary mixtures thereof have been determined. These basic thermodynamic data have been used to improve the predictions of a computer program based on a modified Redlich-Kwong equation of state. The agreement between experiments and final predictions is in general good except for the liquid phase of some binaries containing nitrogen. This discrepancy is postulated to be due to the existence of two liquid phases. © 1979, American Chemical Society. All rights reserved.
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页码:339 / 345
页数:7
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