ABNORMAL STABILITY AND REACTIVITY OF PERFLUOROALKYLAZIRINES AND PERFLUOROALKYLAZIRIDINES

被引：11

作者：

HADDACH, M ^{[1
]}

PASTOR, R ^{[1
]}

RIESS, JG ^{[1
]}

机构：

[1] UNIV NICE,SOPHIA ANTIPOLIS,CHIM MOLEC LAB,CNRS,UNITE RECH,PARC VALROSE,F-06034 NICE,FRANCE

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 14期

关键词：

D O I：

10.1016/S0040-4039(00)88896-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The presence of an F-alkyl chain induces particular reactivity and stability in azirinic and aziridinic rings. The newly synthesized F-alkyl azirine carboxylates undergo addition reactions. The F-alkyl aziridine carboxylates are extremely stable towards both nucleophilic and electrophilic reactants, whether the medium be neutral, acidic or basic. © 1990.

引用

页码：1989 / 1990

页数：2

共 5 条

[1]

BLAIGNON C, 1988, 2ND P WORLD SURF C P, V2, P137

[2] SYNTHESIS AND REACTIVITY OF ETHYL 3-PERFLUOROALKYL-3-ALKYLTHIOPROPENOATES - PERFLUOROALKYLATED THIOPHENES AND BETA-THIOXOESTERS [J].

CHAUVIN, A ;

GREINER, J ;

PASTOR, R ;

CAMBON, A .

TETRAHEDRON, 1986, 42 (02) :663-668

[3]

RIESS JG, 1988, 2ND P WORLD SURF C P, V4, P256

[4]

WADE TN, 1979, TETRAHEDRON LETT, P3953

[5] NITRILE YLIDES AND AZIRINES - GAS-PHASE GENERATION FROM 2,3-DIHYDRO-1,4,2-LAMBDA-5-OXAZAPHOSPHOLES AND MATRIX-ISOLATION [J].

WENTRUP, C ;

FISCHER, S ;

BERSTERMANN, HM ;

KUZAJ, M ;

LUERSSEN, H ;

BURGER, K .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (01) :85-86

← 1 →