REACTIONS OF AS(NME2)3 AND SB(NME2)3 WITH ALUMINUM AND MAGNESIUM ALKYLATING-AGENTS

被引：17

作者：

THOMAS, CJ ^{[1
]}

KRANNICH, LK ^{[1
]}

WATKINS, CL ^{[1
]}

机构：

[1] UNIV ALABAMA,DEPT CHEM,BIRMINGHAM,AL 35294

来源：

POLYHEDRON | 1993年 / 12卷 / 01期

关键词：

D O I：

10.1016/S0277-5387(00)87058-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of aluminum alkyls, R3Al (R = Me, Et, Pr(n), Bu(n) and Bu(i)), with As(NMe2)3 and Sb(NMe2)3 have been used to synthesize the respective tertiary arsines, R3As, and tertiary stibines, R3Sb, in good yields. As(NMe2)3 also reacts with Grignard reagents, RMgX (R = Et, Pr(n), Pr(i), Bu(n), Bu(i), Bu(t), CH2=CH-, CH3CH=H-, Me3SiCH2-, Ph, p-tolyl and mesityl), to give R3As. Complete C-13 and H-1 NMR spectral data on the synthesized R3Sb and [R2AlNMe2]2 are also reported.

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页码：89 / 94

页数：6

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