EVIDENCE FOR THE ALLYL AND SECONDARY CATION INTERMEDIATE ON ADSORPTION OF ALLYL ALCOHOL ON H-ZSM-5 ZEOLITE

被引:25
作者
BIAGLOW, AI [1 ]
GORTE, RJ [1 ]
WHITE, D [1 ]
机构
[1] UNIV PENN,DEPT CHEM,PHILADELPHIA,PA 19104
关键词
D O I
10.1039/c39930001164
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
C-13 NMR spectroscopy is used to show that for surface coverages corresponding to less than one allyl alcohol molecule per Bronsted site in H-ZSM-5, there is evidence for the formation of an allyl carbocation.
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页码:1164 / 1166
页数:3
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