REACTION OF 2-(ETHOXYCARBONYL)PENTADIENYLSILANE UNDER RITTER CONDITION - FORMATION OF ALPHA-METHYLENE-GAMMA-LACTONE BY SELF-CYCLIZATION

被引：5

作者：

KURODA, C

MITSUMATA, N

机构：

来源：

CHEMISTRY LETTERS | 1994年 / 08期

关键词：

D O I：

10.1246/cl.1994.1375

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An acylative C(3)-C(4)-bond cleavage of 4,5-disubstituted-2-trimethylsilylmethyl-penta-2,4-dienoate occurred by treatment with trifluoromethanesulfonic acid in nitriles, while a self-cyclization giving an alpha-methylene-gamma-lactone also occurred when the reactions were carried out in bulky nitriles.

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页码：1375 / 1378

页数：4

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