SKELETAL REARRANGEMENTS INDUCED BY CHEMICAL IONIZATION .1. ANALOGY TO SOLVOLYSIS

被引：4

作者：

REDDY, GS

VAIRAMANI, M

DAS, KG

BUDZIKIEWICZ, H

GREEN, MM

机构：

[1] NATL CHEM LAB,POONA 411008,MAHARASHTRA,INDIA

[2] UNIV COLOGNE,INST ORGAN CHEM,D-5000 COLOGNE 41,FED REP GER

[3] CLARKSON COLL TECHNOL,POTSDAM,NY 13676

来源：

TETRAHEDRON | 1979年 / 35卷 / 22期

关键词：

D O I：

10.1016/0040-4020(79)87052-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In contrast to the usual expectation in chemical ionization (CI) mass spectrometry, the CI spectra of a series of aryl 4-nitro-Δ'-cyclohexenes show very low intensity protonated molecular ions while a major share of the ion current is carried by rearrangement ions. The intervention of a rearrangement long known in the solvolysis of cyclohexenyl carbenium ions can account for the observed CI behaviour. © 1979.

引用

页码：2697 / 2701

页数：5

共 39 条

[1]

BINDRA JS, 1971, INDIAN J CHEM, V9, P388

[2] ELECTRON-IMPACT INDUCED REARRANGEMENT REACTIONS OF ORGANIC MOLECULES [J].