STRUCTURE OF BIS(PARA-METHOXYPHENYLTELLURO)METHANE

被引：4

作者：

DEMATHEUS, M

TORRES, L

PINIELLA, JF

MIRAVITLLES, C

机构：

[1] UNIV AUTONOMA BARCELONA, AREA CRISTALOG, E-08193 BELLATERA, SPAIN

[2] UNIV NACL COLOMBIA, DEPT QUIM, SANTA FE DE BOGOTA, COLOMBIA

[3] INST CIENCIA MAT, E-08028 BARCELONA, SPAIN

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 1991年 / 47卷

关键词：

D O I：

10.1107/S0108270190011167

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

C15H16O2Te2, M(r) = 483.2, orthorhombic, Pbca, a = 6.374 (2), b = 17.069 (2), c = 28.538 (3) angstrom, V = 3105 (1) angstrom 3, Z = 8, D(x) = 2.07 Mg m-3, Mo K-alpha, lambda = 0.71069 angstrom, mu = 3.763 mm-1, F(000) = 1808, T = 293 K, R = 0.046, wR = 0.052 for 1722 observed reflections. Each Te atom in the binuclear molecule is bonded to two different organo groups with Te-C(aliph) 2.149 (6) and 2.131 (6) angstrom; Te-C(arom) 2.115 (6) and 2.105 (7) angstrom; C-Te-C 95.2 (2), 97.8 (2)-degrees; Te-Te distance 3.6632 (9) angstrom. The Te atoms exhibit different surroundings: square-planar geometry for Te1 and T-shaped for Te3.

引用

页码：1264 / 1266

页数：3

共 14 条

[1] SECONDARY BONDING .7. CRYSTAL AND MOLECULAR-STRUCTURES OF DIPHENYLTELLURIUM DICHLORIDE AND PHENYLTELLURIUM TRICHLORIDE [J].