PHOTO-CROSS-LINKABLE AND OPTICALLY-ACTIVE SIDE-CHAIN LIQUID-CRYSTALLINE COPOLYMERS

被引：47

作者：

CHIEN, LC ^{[1
]}

CADA, LG ^{[1
]}

机构：

[1] KENT STATE UNIV,NSF ALCOM CTR,KENT,OH 44242

来源：

MACROMOLECULES | 1994年 / 27卷 / 14期

关键词：

D O I：

10.1021/ma00092a007

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A series of new photo-cross-linkable and optically active side-chain liquid-crystalline copolymers, 1a-e, were prepared from the hydrosilylation reactions of poly(methylhydrosiloxanes) with (S)-3-[2-((4-cyano-4'-biphenyloxy)-2-methylethoxy]propene (2) and the nematogenic monomer 4-methoxyphenyl 4-(6-hexenyloxy)cinnamate (3) in the presence of Speier's catalyst (H2PtCl6.6H2O in propan-2-ol). The copolymers were found to exhibit chiral smectic C phases. Photo-cross-linking these copolymers at their mesomorphic state enhances the thermal stability of the mesophase.

引用

页码：3721 / 3726

页数：6

共 37 条

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