CARBONYL HALIDES OF GROUP-6 TRANSITION METALS .14. SUBSTITUTION DERIVATIVES OF TRIHALOTETRACARBONYL MOLYBDENUM(2) ANIONS

被引：21

作者：

BOWDEN, JA

COLTON, R

机构：

[1] Department of Inorganic Chemistry, University of Melbourne, Parkville, VIC

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1969年 / 22卷 / 05期

关键词：

D O I：

10.1071/CH9690905

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complete series of infstituted halocarbonyl anions [Mo(CO)3RPh3X3]− (where R is P, Sb, As; X is Cl, Br) have been characterized as their tetraethyl-ammonium salts. Each infstituted anion has been prepared by two distinct methods and all of the compounds can exist as two isomers. Except for the α-isomer of [Mo(CO)3PPh3Br3]− these complexes are reported for the first time. © 1969, CSIRO. All rights reserved.

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页码：905 / &

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