SYNTHESIS AND CHARACTERIZATION OF ESTRADIOL AND ESTRADIENONYL DERIVATIVES OF PENTAMETHYLCYCLOPENTADIENYLRUTHENIUM(II)

被引：36

作者：

VICHARD, D ^{[1
]}

GRUSELLE, M ^{[1
]}

AMOURI, H ^{[1
]}

JAOUEN, G ^{[1
]}

机构：

[1] ECOLE NATL SUPER CHIM, UA 403, 11 RUE PIERRE & MARIE CURIE, F-75231 PARIS 05, FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 01期

关键词：

D O I：

10.1039/c39910000046

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The 'C5Me5Ru' moiety coordinates at the A ring of estradiol to give both the alpha and beta isomers of the ketonic form [Ru(C5Me5)(eta-5-estradienonyl)] (1a and 1b respectively) and the alpha isomer of the phenolic form [Ru(C5Me5)(eta-6-estradiol)][PF6] 2a; 1a reacts with HPF6 to give quantitatively 2a, but in the presence of NEt3 1a was regenerated.

引用

页码：46 / 48

页数：3

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