TOTAL SYNTHESIS OF STEROID ANALOGS BY ORGANOMETALLIC PROCEDURES

被引：8

作者：

CHIUSOLI, GP

SALERNO, G

BERGAMASCHI, E

ANDREETTI, GD

BOCELLI, G

SGARABOTTO, P

机构：

[1] UNIV PARMA,CNR,IST STRUTTURIST CHIM,I-43100 PARMA,ITALY

[2] UNIV PARMA,CNR,CTR STUDIO STRUTTURIST DIFFATTOMETR,I-43100 PARMA,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 177卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)92350-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of steroid-type structures has been achieved by means of a series of coupling, alkylation, carbonylation and cyclization steps, all of which involve organometallic reagents or catalysts. The ring closures are effected with carbonyl complexes of nickel and with tin tetrachloride. The X-ray structure of the main product resulting from two successive cyclizations is described. © 1979.

引用

页码：245 / 253

页数：9

共 13 条

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[10] ALPHA ANIONS OF CARBOXYLIC-ACIDS .2. FORMATION AND ALKYLATION OF ALPHA-METALATED ALIPHATIC ACIDS
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