COMBUSTION RATES OF PULVERIZED COAL PARTICLES IN HIGH-TEMPERATURE HIGH-OXYGEN CONCENTRATION ATMOSPHERE

被引:26
作者
SAITO, M [1 ]
SADAKATA, M [1 ]
SATO, M [1 ]
SOUTOME, T [1 ]
MURATA, H [1 ]
OHNO, Y [1 ]
机构
[1] NIPPON KOKAN KK,KAWASAKI KU,KAWASAKI 210,JAPAN
关键词
D O I
10.1016/0010-2180(91)90022-4
中图分类号
O414.1 [热力学];
学科分类号
摘要
Combustion characteristics of pulverized coal particles at particle temperatures over 1800-degrees-C and oxygen concentration of 40%-80% were investigated using a high-temperature drop furnace. The results demonstrate that the ignition delay time and burnout time are less than 10 and 50 ms, respectively, in the case of combustion under a high-temperature/high-oxygen concentration atmosphere. It was found that the char combustion rate was controlled by gas film diffusion, and the apparent activation energy was about 8.4 kJ/mol. Also, the rotation of pulverized coal particles was observed during early-stage of combustion and the rotation frequency reached 3000-5000 cycles/s. The combustion rate of volatile matter was remarkably increased within the range of particle temperature over 2100-degrees-C. The apparent activation energy of the combustion rate of volatile matter was increased with increasing particle temperature and oxygen concentration. The value of activation energy changed from 109.2 kJ/mol for particle temperature 1800-2100-degrees-C and oxygen concentration 40%-50% to 336 kJ/mol for particle temperature over 2500-degrees-C and oxygen concentration 70%-80%.
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页码:1 / 12
页数:12
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