THIOACYLPHOSPHINIDENE

被引：20

作者：

MARKL, G ^{[1
]}

HOLZL, W ^{[1
]}

KALLMUNZER, A ^{[1
]}

ZIEGLER, ML ^{[1
]}

NUBER, B ^{[1
]}

机构：

[1] UNIV HEIDELBERG,INST ANORGAN CHEM,W-6900 HEIDELBERG,GERMANY

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 31期

关键词：

D O I：

10.1016/S0040-4039(00)60099-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2-Chloro-3-phenyl-3-trimethylsilyl-thiaphosphirane (5) opens the ring via the thiaphosphirene to give a thiocarbonylphosphinidene - and not a phosphaethynesulfide - as an intermediate 1,3-dipole.

引用

页码：4421 / 4424

页数：4

共 5 条

[1] THERMAL-DECOMPOSITION OF 1,2,3,4-THIATRIAZOLES - QUESTION OF THIOACYL AZIDE AND THIOACYLNITRENE INTERMEDIATES [J].

HOLM, A ;

CARLSEN, L ;

LARSEN, E .

JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (25) :4816-4822

[2]

HUISGEN R, 1964, TETRAHEDRON LETT, V22, P1409

[3] 2-CHLORO-1-THIA-2-PHOSPHIRANES - SYNTHESIS AND REACTIONS - ELUCIDATIONS ON THE 1,3-DIPOLE PHC+=P-S- [J].

MARKL, G ;

HOLZL, W .

TETRAHEDRON LETTERS, 1989, 30 (34) :4501-4504

[4] PHOTOCHEMICAL ADDITION OF METHYL AZIDOFORMATE TO 2-BUTYNE [J].

MEINWALD, J ;

AUE, DH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (12) :2849-&

[5] PHOSPHORUS-COMPOUNDS WITH UNUSUAL COORDINATION .2. 1,2,3,4-TRIAZAPHOSPHOLES BY [3+2]-CYCLOADDITION OF AZIDES TO A STABLE PHOSPHAALKYNE [J].

ROSCH, W ;

FACKLAM, T ;

REGITZ, M .

TETRAHEDRON, 1987, 43 (14) :3247-3256

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