PYROLYSIS OF REFUSE DERIVED FUEL - KINETIC MODELING FROM PRODUCT COMPOSITION

被引：5

作者：

ROVATTI, M ^{[1
]}

CONVERTI, A ^{[1
]}

BISI, M ^{[1
]}

FERRAIOLO, G ^{[1
]}

机构：

[1] UNIV GENOA,INST CHEM ENGN SCI & TECHNOL,VIA OPERA PIA 15,I-16145 GENOA,ITALY

来源：

JOURNAL OF HAZARDOUS MATERIALS | 1994年 / 36卷 / 01期

关键词：

D O I：

10.1016/0304-3894(93)E0048-7

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The pyrolysis of RDF has been studied in this work by analyzing the gaseous product composition at different temperatures and reaction times. The formation of each gaseous component in the pyrolysis gas has been described by supposing the occurrence of simultaneous first-order reactions as well as neglecting possible interactions among them. This kinetic approach allows the calculation of the rate constants of formation for each product at different temperatures and the related thermodynamic quantities and the formulation of hypotheses on the mechanisms involved in the pyrolysis. Concerted mechanisms are proposed for the formation of most of the detected gaseous products.

引用

页码：19 / 33

页数：15

共 17 条

[1] KINETICS OF REACTIONS INVOLVED IN PYROLYSIS OF CELLULOSE .2. THE MODIFIED KILZER-BROIDO MODEL [J].

AGRAWAL, RK .

CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1988, 66 (03) :413-418

[2] KINETICS OF REACTIONS INVOLVED IN PYROLYSIS OF CELLULOSE .1. THE 3-REACTION MODEL [J].

AGRAWAL, RK .

CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1988, 66 (03) :403-412

[3]

BISI M, 1989, THESIS GENOA U GENOA

[4] GAS SOLID PYROLYSIS OF TIRE WASTES - KINETICS AND MATERIAL BALANCES OF BATCH PYROLYSIS OF USED TIRES [J].

BOUVIER, JM ;

CHARBEL, F ;

GELUS, M .

RESOURCES AND CONSERVATION, 1987, 15 (03) :205-214

[5] EUROPEAN-EXPERIENCE IN THE PYROLYSIS AND GASIFICATION OF SOLID-WASTES [J].

BUEKENS, AG ;

SCHOETERS, JG .

CONSERVATION & RECYCLING, 1986, 9 (03) :253-269

[6] CHAIN REACTION MECHANISM OF CELLULOSE PYROLYSIS [J].

CHATTERJEE, PK .

JOURNAL OF APPLIED POLYMER SCIENCE, 1968, 12 (08) :1859-+

[7]

FROST AA, 1963, INETICS MECHANISM, P98

[8] KINETIC MODELING OF THE PYROLYSIS OF BIOMASS AND BIOMASS COMPONENTS [J].

KOUFOPANOS, CA ;

MASCHIO, G ;

LUCCHESI, A .

CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1989, 67 (01) :75-84

[9] MODELING OF THE PYROLYSIS OF BIOMASS PARTICLES - STUDIES ON KINETICS, THERMAL AND HEAT-TRANSFER EFFECTS [J].

KOUFOPANOS, CA ;

PAPAYANNAKOS, N ;

MASCHIO, G ;

LUCCHESI, A .

CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1991, 69 (04) :907-915

[10] KINETICS OF PYROLYSIS OF CELLULOSE IN TEMPERATURE RANGE 250-300 DEGREES C [J].

LIPSKA, AE ;

PARKER, WJ .

JOURNAL OF APPLIED POLYMER SCIENCE, 1966, 10 (10) :1439-&

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