PHOTOISOMERIZATION DYNAMICS OF STILBENES IN POLAR-SOLVENTS

被引:60
作者
WALDECK, DH
机构
[1] Department of Chemistry, University of Pittsburgh, Pittsburgh
关键词
D O I
10.1016/0167-7322(93)80051-V
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Recent studies of the photoisomerization kinetics of trans-stilbene and substituted stilbenes in polar solvents are discussed. The experimental studies and their comparison with reaction rate theories are reviewed. Recent theoretical development of stochastic models of reaction in more than one dimension is discussed and compared with the experimental findings at a semiquantitative level. The qualitative characteristics of the reactive process are discussed.
引用
收藏
页码:127 / 148
页数:22
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