SPECTROELECTROCHEMICAL STUDY OF THE RADICAL CATION PRODUCED FROM A 1,3-DIPHENYLPYRAZOLINE DERIVATIVE

被引：17

作者：

GENIES, M ^{[1
]}

DIAZ, AF ^{[1
]}

机构：

[1] IDM RES LAB, SAN JOSE, CA 95193 USA

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1979年 / 98卷 / 02期

关键词：

D O I：

10.1016/S0022-0728(79)80269-7

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The oxidation of PH2 was studied spectroelectrochemically. The generated radical cation yields dimeric product which is subsequently oxidized in the same potential range. Dimer formation from PH2 radical cation is not influenced by the presence of added base in the solution which is in contrast with previous observations with analogous systems. Quantitative estimates for some of the reaction rates is provided. © 1979 Elsevier Sequoia S.A., Lausanne.

引用

页码：305 / 317

页数：13

共 23 条

[1] ELECTRODIMERIZATION .7. ELECTRODE AND SOLUTION ELECTRON TRANSFERS IN RADICAL-SUBSTRATE COUPLING MECHANISM - DISCRIMINATIVE CRITERIA FROM OTHER MECHANISMS IN VOLTAMMETRIC STUDIES (LINEAR SWEEP, ROTATING-DISK, POLAROGRAPHY) [J].