STEREOCHEMISTRY AT CARBON FOR ALKYL MIGRATION TO OXYGEN IN THE REARRANGEMENT OF A TERT-BUTYLPEROXY ALKYL DERIVATIVE OF PERMETHYLHAFNOCENE

被引：8

作者：

COUGHLIN, EB ^{[1
]}

BERCAW, JE ^{[1
]}

机构：

[1] CALTECH,ARTHUR AMOS NOYES LAB CHEM PHYS,ARNOLD & MABEL BECKMAN LABS CHEM SYNTHESIS,PASADENA,CA 91125

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 01期

关键词：

D O I：

10.1021/om00037a076

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Neohexyl migration from hafnium to oxygen for threo- and erythro-(eta(5)-C5Me5)2Hf(CHDCHDCMe3)-(OOCMe3) to form threo- and erythro-(eta(5)-C5Me5)2Hf-(OCHDCHDCMe3)(OCMe3) has been found to occur with retention of configuration at the migrating carbon center.

引用

页码：465 / 467

页数：3

共 21 条

[1]

BLACKBURN TF, 1975, TETRAHEDRON LETT, P3041

[2] STEREOCHEMISTRY OF REACTIONS AT CARBON-TRANSITION METAL SIGMA BONDS - (CH3)3CCHDCHDFE(CO)2C5H5 [J].