PHOSPHONIUM SALT METHODOLOGY FOR THE SYNTHESIS OF PHOSPHORIC MONOESTERS AND DIESTERS AND ITS APPLICATION TO SELECTIVE PHOSPHORYLATION

被引：36

作者：

WATANABE, Y

INADA, E

JINNO, M

OZAKI, S

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Ehime University, Matsuyama

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 03期

关键词：

D O I：

10.1016/0040-4039(93)85111-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of an alcohol with a trialkyl phosphite in the presence of pyridinium bromide perbromide and triethylamine afforded the phosphoric triester in good yield, which can be transformed to the phosphoric monoester or diester. The method was applied to selective phosphorylation aiming at a convenient synthesis of phosphatidyl myo-inositol derivatives.

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页码：497 / 500

页数：4

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