LINE-SHAPES OF STRONGLY RADIATION-DAMPED NUCLEAR-MAGNETIC-RESONANCE SIGNALS

被引:48
作者
MAO, XA
YE, CH
机构
[1] Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics, Chinese Academy of Sciences, Wuhan 430071
关键词
D O I
10.1063/1.465727
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Line shapes of strongly radiation-damped nuclear magnetic resonance (NMR) signals are theoretically analyzed. Analytical expressions for the radiation-damped signals in the frequency domain are reported for the first time. It is shown that the line shapes are generally dependent on the flip angle theta0 of the excitation pulse. In the range of 0 less-than-or-equal-to theta0 < pi, the peak height increases linearly, but the linewidth decreases monotonically with the flip angle. An oscillating feature is predicted for the line shape when theta0 > pi/2. The theoretical predictions are confirmed by the experimental results.
引用
收藏
页码:7455 / 7462
页数:8
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