CATIONIC PALLADIUM(II), PLATINUM(II), AND RHODIUM(I) COMPLEXES AS ACETALIZATION CATALYSTS

被引：55

作者：

GORLA, F ^{[1
]}

VENANZI, LM ^{[1
]}

机构：

[1] SWISS FED INST TECHNOL,ANORGAN CHEM LAB,UNIV STR 6,CH-8092 ZURICH,SWITZERLAND

来源：

HELVETICA CHIMICA ACTA | 1990年 / 73卷 / 03期

关键词：

D O I：

10.1002/hlca.19900730317

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of [Pd(H2O)2(Ph2PCH2CH2PPh2)] (CF3SO3)2 as a catalyst for the acetalisation of a variety of aldehydes and ketones and for trans‐acetalisation is described. It is also shown that Pt(H2O)2(PH2PCH2CH2PPh2) (CF3SO3)2 is at least as effective as the corresponding Pd compound, while much lower reaction rates are observed with [Rh(MeOH)2(Ph2PCH2CH2PPh2)] [BF4]. Copyright © 1990 Verlag GmbH & Co. KGaA, Weinheim

引用

页码：690 / 697

页数：8

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