EXCESS GIBBS ENERGIES AND EXCESS VOLUMES OF METHYL TERT-BUTYL ETHER (MTBE) + DICHLOROMETHANE, + CHLOROFORM, OR + TETRACHLOROMETHANE

被引：22

作者：

MATO, FA ^{[1
]}

BERRO, C ^{[1
]}

PENELOUX, A ^{[1
]}

机构：

[1] FAC SCI LUMINY,CHIM PHYS LAB,F-13288 MARSEILLE 9,FRANCE

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1991年 / 36卷 / 03期

关键词：

D O I：

10.1021/je00003a001

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Isothermal P-x-y and excess volume data for methyl tert-butyl ether (MTBE) + dichloromethane, MTBE + chloroform, and MTBE + tetrachloromethane are measured. The vapor-liquid equilibrium data were reduced according to the maximum-likelihood principle. The system MTBE + tetrachloromethane shows an almost ideal behavior, while MTBE + chloroform shows strong negative deviations from ideality and exhibits a maximum-boiling azeotrope. The system MTBE + dichloromethane presents an intermediate behavior, with moderate negative deviations.

引用

页码：259 / 262

页数：4

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