SYNTHESIS, STRUCTURE, AND REACTIVITY OF A NEW SERIES OF TITANIUM ETA-2-OLEFIN AND ETA-2-KETONE COMPLEXES

被引：67

作者：

HILL, JE ^{[1
]}

FANWICK, PE ^{[1
]}

ROTHWELL, IP ^{[1
]}

机构：

[1] PURDUE UNIV,DEPT CHEM,1393 BROWN BLDG,W LAFAYETTE,IN 47907

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 05期

关键词：

D O I：

10.1021/om00041a006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Fragmentation of the titanacyclopentane ring in [(Ar"O)2Ti(CH2)4] (Ar"O = 2,6-diphenylphenoxide) occurs upon addition of PMe3 to yield the eta-2-ethylene complex [(Ar"O)2Ti(eta-2-C2H4)(PMe3)] (1). The reactivity of 1 and its eta-2-propene analogue toward Ph2C=O has been investigated.

引用

页码：1771 / 1773

页数：3

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