THE 1ST COMPLEX WITH A SIGMA-2-PI-4 TRIPLE BOND BETWEEN VANADIUM ATOMS IN A LIGAND FRAMEWORK OF FOURFOLD SYMMETRY-[V2((P-CH3C6H4)NC(H)N(P-C6H4CH3))4]

被引：50

作者：

COTTON, FA ^{[1
]}

DANIELS, LM ^{[1
]}

MURILLO, CA ^{[1
]}

机构：

[1] UNIV COSTA RICA,DEPT CHEM,SAN JOSE,COSTA RICA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 06期

关键词：

D O I：

10.1002/anie.199207371

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The long quest for a V-V triple bond has finally(~)met with success as shown by the synthesis of the title compound 1. A short intermetallic distance and high magnetic anisotropy indicate strong interaction between the vanadium centers, R = p-CH3C6H4.

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页码：737 / 738

页数：2

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