NMR-STUDIES OF HYDROGEN DIFFUSION IN BETA-LANI5-YALY HYDRIDES

被引：56

作者：

BOWMAN, RC ^{[1
]}

GRUEN, DM ^{[1
]}

MENDELSOHN, MH ^{[1
]}

机构：

[1] ARGONNE NATL LAB,DIV CHEM,ARGONNE,IL 60439

来源：

SOLID STATE COMMUNICATIONS | 1979年 / 32卷 / 07期

关键词：

D O I：

10.1016/0038-1098(79)90362-4

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

Proton relaxation times have been measured in β-phase LaNi5-yAlyHx, where 0<y<1.2, to determine the role of Al on hydrogen diffusion. Al substitution significantly increases the observed activation energy with a corresponding 100-fold decrease in the room temperature (300K) diffusion constant between y=0 and y=1.2. Comparisons are also made with previous studies of β-LaNi5Hx and possible diffusion mechanisms are suggested. © 1979.

引用

页码：501 / 506

页数：6

共 20 条

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