ASYMMETRIC DARZENS CONDENSATION ON CHIRAL ETA-6CR(CO)3 COMPLEXED BENZALDEHYDES

被引：30

作者：

BALDOLI, C ^{[1
]}

DELBUTTERO, P ^{[1
]}

MAIORANA, S ^{[1
]}

机构：

[1] CTR CNR,I-20133 MILAN,ITALY

来源：

TETRAHEDRON | 1990年 / 46卷 / 23期

关键词：

D O I：

10.1016/S0040-4020(01)90079-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Enantioselective Darzens condensation has been achieved from optically active ortho substituted benzaldehyde(tricarbonyl)chromium complexes. The enantiomeric excesses were very high with 2-methoxy and 2-chloro benzaldehyde(tricarbonyl)chromium and the corresponding epoxides obtained were nearly optically pure. © 1990.

引用

页码：7823 / 7830

页数：8

共 17 条

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